[1]王潤國,周鑫鑫,雷巍巍,等.衣康酸的制備及其在高分子材料中的應(yīng)用[J].中國材料進(jìn)展,2012,(12):040-45.[doi:10.7502/j.issn.1674-3962.2012.12.06]
WANG Runguo,ZHOU Xinxin,LEI Weiwei,et al.Production of Itaconic Acid and Its Applications in Polymer Materials[J].MATERIALS CHINA,2012,(12):040-45.[doi:10.7502/j.issn.1674-3962.2012.12.06]
點擊復(fù)制
衣康酸的制備及其在高分子材料中的應(yīng)用(
)
中國材料進(jìn)展[ISSN:1674-3962/CN:61-1473/TG]
- 卷:
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- 期數(shù):
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2012年第12期
- 頁碼:
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040-45
- 欄目:
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- 出版日期:
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2012-12-31
文章信息/Info
- Title:
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Production of Itaconic Acid and Its Applications in Polymer Materials
- 作者:
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王潤國; 周鑫鑫; 雷巍巍; 張立群
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（1 北京化工大學(xué) 北京市新型高分子材料制備與成型加工重點實驗室，北京 100029)
(2北京化工大學(xué) 納米材料先進(jìn)制備技術(shù)與應(yīng)用科學(xué)教育部重點實驗室，北京 100029）
- Author(s):
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WANG Runguo1; ZHOU Xinxin1; LEI Weiwei1; ZHANG Liqun1; 2
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（1. Key Laboratory of Beijing City on Preparation and Processing of Novel Polymer Materials, Beijing University of Chemical Technology, Beijing 100029, China)(2.Key Laboratory for Nanomaterials, Ministry of Education, Beijing University of Chemical Technology,Beijing 100029, China）
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- 關(guān)鍵詞:
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衣康酸; 制備; 高分子材料; 應(yīng)用
- DOI:
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10.7502/j.issn.1674-3962.2012.12.06
- 文獻(xiàn)標(biāo)志碼:
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A
- 摘要:
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介紹了衣康酸的制備工藝。其主要可通過微生物發(fā)酵法、檸檬酸合成法和順酐合成法制得。衣康酸分子中含有2個羧基和1個碳碳雙鍵，可通過與其他單體共聚合制備新型高分子材料。如將衣康酸與丙烯腈共聚可制備改性聚丙烯腈原絲；將衣康酸與二元醇縮聚可制備新型聚酯材料；將衣康酸、丙二醇和癸二酸縮聚可制備具有形狀記憶功能的新型生物基聚胺材料等等。另外，利用衣康酸多官能團(tuán)特點，還可以對部分高分子材料靈活改性。如衣康酸接枝聚烯烴和尼龍改善材料的相容性；衣康酸改性丁苯膠乳可大大提高其機械穩(wěn)定性、抗凍性等性能。由于石化資源的不可再生性，伴隨著衣康酸的產(chǎn)能增加，成本降低，利用衣康酸單體合成的新型高分子材料具有廣闊的應(yīng)用前景。
- Abstract:
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The paper gave a brief introduction to the preparation of itaconic acid. It could be produced by microorganism fermentation method, critic acid synthesis method and maleic anhydride synthesis method. Itaconic acid contains two carboxyl groups and double bonds, which can be used for synthesizing polymers and copolymers with other monomers. For example, itaconic acid could be copolymeized with acrylonitrile to prepare caron fiber and copolymerized with dihydric alcohol to prepare polyester. Many polymer materials can also be modified by itconic acid. Polyolefin and nylon materials could be grafted by itaconic acid to improve the compatibility, and styrenebutadiene latex could be modified by itaconic acid to improve its performance greatly. Due to the nonrenewablity of fossil energy, as the capacity of itconic acid increasing, the biobased material like itaconic acid has a bright future.
更新日期/Last Update:
2012-12-28