[1]宋靜靜,李勇,楊永珍,等.碳微球表面包覆氧化鋅的制備與表征[J].中國(guó)材料進(jìn)展,2012,(12):045-50.[doi:10.7502/j.issn.1674-3962.2012.12.07]
SONG Jingjing,LI Yong,YANG Yongzhen,et al. Preparation and Characterization of ZnOEncapsulated Carbon Microsphere Composites[J].MATERIALS CHINA,2012,(12):045-50.[doi:10.7502/j.issn.1674-3962.2012.12.07]
點(diǎn)擊復(fù)制
碳微球表面包覆氧化鋅的制備與表征(
)
中國(guó)材料進(jìn)展[ISSN:1674-3962/CN:61-1473/TG]
- 卷:
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- 期數(shù):
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2012年第12期
- 頁(yè)碼:
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045-50
- 欄目:
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- 出版日期:
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2012-12-31
文章信息/Info
- Title:
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Preparation and Characterization of ZnOEncapsulated Carbon Microsphere Composites
- 作者:
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宋靜靜; 李勇; 楊永珍; 劉旭光; 許并社
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( 1 太原理工大學(xué) 新材料界面科學(xué)與工程教育部重點(diǎn)實(shí)驗(yàn)室，山西 太原030024)
( 2 太原理工大學(xué)材料科學(xué)與工程學(xué)院，山西 太原030024)
( 3 太原理工大學(xué) 新材料工程技術(shù)研究中心，山西 太原030024)
( 4 太原理工大學(xué)化學(xué)化工學(xué)院，山西 太原030024)
- Author(s):
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SONG Jingjing1; 2; LI Yong1; 2; YANG Yongzhen1; 3; LIU Xuguang1; 4; XU Bingshe1; 3
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- 關(guān)鍵詞:
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復(fù)合材料; 碳微球; 氧化鋅; 表征
- DOI:
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10.7502/j.issn.1674-3962.2012.12.07
- 文獻(xiàn)標(biāo)志碼:
-
A
- 摘要:
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利用化學(xué)氣相沉積法，制備了直徑約370 nm的碳微球（CMSs）；然后用濃HNO3和H2O2對(duì)其進(jìn)行氧化修飾，使其表面接上羥基等含氧官能團(tuán)；最后再與醋酸鋅和三乙醇胺反應(yīng)，在CMSs表面包覆ZnO層形成ZnO/CMSs復(fù)合物，在此過(guò)程中考察了醋酸鋅和三乙醇胺物質(zhì)的量比和反應(yīng)時(shí)間對(duì)復(fù)合物的影響。采用場(chǎng)發(fā)射掃描電子顯微鏡、紅外光譜、熱重分析儀和X射線衍射儀等對(duì)各階段產(chǎn)物進(jìn)行了形貌和結(jié)構(gòu)的表征與分析。結(jié)果表明：醋酸鋅和三乙醇胺的物質(zhì)的量比為1 2，反應(yīng)時(shí)間為2 h時(shí)，得到的ZnO/CMSs復(fù)合物外觀形貌光滑，包覆均勻且不易脫落。
- Abstract:
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Carbon microspheres (CMS) with size of 370 nm were synthesized by chemical vapor deposition. Then CMSs were oxidized with a mixture of concentrated HNO3 and H2O2 Finally, CMSs were covered with ZnO to form ZnO/CMS composites after CMSs were reacted with zinc acetate and triethanolamine. The influences of molar ratio of zinc acetate to triethanolamine and reaction time were investigated. The morphology and structure of the products were characterized by field emission scanning electron microscopy, Fourier transformation infrared spectrometry, thermogravimetry and Xray diffraction. The results show that the obtained ZnO/CMS composites with uniform size had smooth surfaces and the interaction between ZnO and CMSs was stronger when the molar ratio of zinc acetate to triethanolamine was 1 2 and the reaction time was 2 h.
更新日期/Last Update:
2012-12-28