[1]蘇慶梅,杜高輝,郭俊杰,等.原位透射電鏡技術(shù)在電化學(xué)儲能領(lǐng)域的研究進(jìn)展[J].中國材料進(jìn)展,2020,(7-8):559-575.[doi:10.7502/j.issn.1674-3962.202006027]
SU Qingmei,DU Gaohui,GUO Junjie,et al.Recent Progress of in situ Transmission Electron Microscopy on Electrochemical Energy Storage[J].MATERIALS CHINA,2020,(7-8):559-575.[doi:10.7502/j.issn.1674-3962.202006027]
點(diǎn)擊復(fù)制
原位透射電鏡技術(shù)在電化學(xué)儲能領(lǐng)域的研究進(jìn)展(
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中國材料進(jìn)展[ISSN:1674-3962/CN:61-1473/TG]
- 卷:
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- 期數(shù):
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2020年第7-8期
- 頁碼:
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559-575
- 欄目:
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- 出版日期:
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2020-08-30
文章信息/Info
- Title:
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Recent Progress of in situ Transmission Electron Microscopy on Electrochemical Energy Storage
- 文章編號:
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1674-3962(2020)07-0559-17
- 作者:
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蘇慶梅1; 杜高輝1; 郭俊杰2; 馬淑芳1; 余愿1; 許并社1; 2
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（1. 陜西科技大學(xué) 材料原子·分子科學(xué)研究所, 陜西 西安 710016）（2. 太原理工大學(xué) 新材料界面科學(xué)與工程教育部重點(diǎn)實(shí)驗(yàn)室，山西 太原 030024）
- Author(s):
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SU Qingmei1; DU Gaohui1; GUO Junjie2; MA Shufang1; YU Yuan1; XU Bingshe1; 2
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(1. Materials Institute of Atomic and Molecular Science, Shaanxi University of Science and Technology, Xi‘a(chǎn)n 710016, China) (2. Key Laboratory of Interface Science and Engineering in Advanced Materials of Ministry of Education, Taiyuan University of Technology, Taiyuan 030024, China)
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- 關(guān)鍵詞:
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原位透射電鏡; 電化學(xué)儲能; 電極材料; 電化學(xué)行為; 儲能機(jī)制
- Keywords:
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in situ TEM; electrochemical energy storage; electrode materials; electrochemical behavior; energy storage mechanism
- 分類號:
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TN16；TM912
- DOI:
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10.7502/j.issn.1674-3962.202006027
- 文獻(xiàn)標(biāo)志碼:
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A
- 摘要:
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理解電極材料的微觀電化學(xué)行為、微觀結(jié)構(gòu)演變和反應(yīng)機(jī)理，對開發(fā)高性能電化學(xué)儲能材料具有重要意義，并有望為優(yōu)化高性能電化學(xué)儲能器件的設(shè)計(jì)提供幫助。在透射電子顯微鏡（TEM）中構(gòu)建微型電池，可以直接觀察在電池工作狀態(tài)下電極材料的形貌、成分和微觀結(jié)構(gòu)演變，從動力學(xué)角度理解電極材料轉(zhuǎn)化和存儲的過程和機(jī)制，構(gòu)建電極材料微觀結(jié)構(gòu)宏觀性能的構(gòu)效關(guān)系。綜述了近年來利用原位TEM研究鋰離子電池重要電極材料、鋰硫電池和鋰空氣電池的最新研究進(jìn)展，討論并展望了原位TEM技術(shù)在電化學(xué)儲能領(lǐng)域的未來發(fā)展趨勢。原位TEM技術(shù)對于研究理解在電池工作狀態(tài)下電極材料的電化學(xué)反應(yīng)行為和機(jī)理具有重要的價(jià)值，對于深入理解電池失效過程和設(shè)計(jì)高性能電池具有重要的指導(dǎo)意義。
- Abstract:
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Understanding the microelectrochemical behavior, microstructure evolution and reaction mechanism of electrode materials is of great significance to explore high-performance electrochemical energy storage materials, and is expected to optimize the design of high-performance electrochemical energy storage devices. By constructing a micro-battery in transmission electron microscope (TEM), the morphology, composition and microstructure evolution of electrode materials in the working state of the battery can be directly observed, which can help us understand the process and mechanism of electrode material during the conversion and storage process from the viewpoints of dynamics, and construct the relationship between microstructure and macro-performance. In this review, the recent research progress of the important materials of lithium-ion batteries, lithium-sulfur batteries and lithium-air batteries by using in situ TEM techniques are summarized. Finally, perspectives on future directions on the application of in situ TEM in electrochemical energy storage studies are provided. In situ TEM has important research value for understanding the electrochemical reaction behavior and mechanism of electrode materials in the working state of the battery, and has important guiding significance for understanding the failure process of the battery and designing high-performance batteries.
備注/Memo
- 備注/Memo:
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收稿日期：2020-06-22 基金項(xiàng)目：國家自然科學(xué)基金資助項(xiàng)目（21674003，91427304）第一作者：蘇慶梅，女，1985年生，教授，博士生導(dǎo)師通訊作者：許并社，男，1955年生，教授，博士生導(dǎo)師， Email:xubingshe@sust.edu.cn
更新日期/Last Update:
2020-06-28