文章信息/Info

Title:

Research Progress on Preparation of Sm alloy by Molten Salt Electrolysis

作者:

康佳; 劉玉寶; 于兵; 黃海濤; 張全軍; 閆奇操*

（包頭稀土研究院白云鄂博稀土資源研究與綜合利用國(guó)家重點(diǎn)實(shí)驗(yàn)室，內(nèi)蒙古，包頭，014030）

Author(s):

Kang Jia;  Liu Yu-bao;  Yu Bing;  Huang Hai-tao;  Zhang Quan-jun;  Yan Qi-cao*

(State Key Laboratory of Baiyunobo Rare Earth Resource Researches and Comprehensive Utilization, Baotou Research Institute of Rare Earths, Baotou, 014030, China)

關(guān)鍵詞:

熔鹽電解法; Sm合金; 稀土; 電化學(xué)行為; 生成規(guī)律

Keywords:

Molten salt electrolysis;  Sm alloy;  Rare earth;  Electrochemical behavior;  Formation rule

文獻(xiàn)標(biāo)志碼:

A

摘要:

稀土釤是變價(jià)稀土元素，所以Sm合金具有它自身所獨(dú)有的特性，使其成為一種極具潛力的功能材料，常被應(yīng)用于稀土永磁、儲(chǔ)氫、發(fā)光以及航空航天等材料領(lǐng)域。本文系統(tǒng)的比較了現(xiàn)階段制備Sm合金方法的優(yōu)缺點(diǎn)，其中熔鹽電解法制備Sm合金具有產(chǎn)物更加純凈、低成本、連續(xù)作業(yè)等優(yōu)點(diǎn)，使該法成為近期學(xué)者的研究熱點(diǎn)。然后，重點(diǎn)闡述了熔鹽電解法制備Sm-Al、Sm-Cu、Sm-Co、Sm-Ni和Sm-Fe合金的最新研究進(jìn)展及存在的問(wèn)題，介紹了Sm離子在熔鹽中的電化學(xué)行為及Sm合金在陰極上的生成規(guī)律，并提出了該方法進(jìn)一步向產(chǎn)業(yè)化方面發(fā)展的方向。

Abstract:

Samarium alloy is considered to be a potential function material, which has its changeable electrovalence character, is widely used as permanent-magnetic, hydrogen-storage, luminescent and aerospace materials. In this paper, the advantages and disadvantages of method, which were used to prepared Sm alloy, were compared. In contrast, the molten salt electrolysis has the advantages of cleaner products, inexpensive, and continuous production, becomes a focus in current research. The research progress and existing problems of Sm-Al, Sm-Cu, Sm-Co, Sm-Ni and Sm-Fe alloys prepared by molten salt electrolysis were emphatically described, and the electrochemical behaviors of Sm3+ and deposition process of Sm alloy were introduced. The direction of industrialization development was also put forward.