文章信息/Info

Title:

Research Progress and Development Trends of Magnesium-Based (or Magnesium-Containing)Hydrogen Storage Materials

文章編號(hào):

1674-3962(2024)12-1064-13

作者:

王齊森; 胡文強(qiáng); 馬仲亮; 王飛; 劉洋; 夏廣林; 宋云; 方方; 余學(xué)斌; 張慶安; 孫大林

1. 復(fù)旦大學(xué)材料科學(xué)系，上海 200433 2. 安徽工業(yè)大學(xué)材料科學(xué)與工程學(xué)院，安徽 馬鞍山243002

Author(s):

WANG Qisen;  HU Wenqiang;  MA Zhongliang;  WANG Fei;  LIU Yang; XIA Guanglin;  SONG Yun;  FANG Fang;  YU Xuebin; ZHANG Qingan;  SUN Dalin

1. Department of Materials Science, Fudan University, Shanghai 200433, China 2. School of Materials Science and Engineering, Anhui University of Technology, Maanshan 243002, China

關(guān)鍵詞:

儲(chǔ)氫合金; 配位氫化物; 外場(chǎng); 成分優(yōu)化; 結(jié)構(gòu)調(diào)整

Keywords:

hydrogen storage alloys;  coordination hydrides;  external field;  composition optimization;  structural adjustment

分類(lèi)號(hào):

TG139+.7；TG146.22

DOI:

10.7502/j.issn.1674-3962.202407015

文獻(xiàn)標(biāo)志碼:

A

摘要:

鎂（含鎂）系儲(chǔ)氫材料作為固態(tài)儲(chǔ)氫技術(shù)的工作介質(zhì)，具有高重量?jī)?chǔ)氫密度和高體積儲(chǔ)氫密度的突出優(yōu)勢(shì)，但其吸/放氫溫度高、速率慢、可逆性差等難點(diǎn)問(wèn)題一直沒(méi)有得到有效解決，嚴(yán)重阻礙了其實(shí)際應(yīng)用。按照化學(xué)鍵性質(zhì)的區(qū)別，鎂（含鎂）系儲(chǔ)氫材料可分為合金和配位化合物兩大類(lèi)。過(guò)去幾十年的研究工作主要集中在通過(guò)改變成分和結(jié)構(gòu)、加入摻雜（催化）劑、構(gòu)建微納結(jié)構(gòu)和失穩(wěn)體系等手段來(lái)解決這些問(wèn)題。但從實(shí)際效果上來(lái)看，在改善動(dòng)力學(xué)方面的進(jìn)展要大于熱力學(xué)方面，使用鎂（含鎂）系儲(chǔ)氫材料的過(guò)程中仍需要通過(guò)傳統(tǒng)電加熱的方式提供額外能量，以克服吸/放氫反應(yīng)的熱力學(xué)和動(dòng)力學(xué)能壘，這導(dǎo)致了能量轉(zhuǎn)化效率降低。最新的研究表明，通過(guò)直接或間接地利用非電加熱形式（太陽(yáng)能和工業(yè)余熱）的外場(chǎng)能量，有望解決能效低的問(wèn)題，為鎂（含鎂）系儲(chǔ)氫材料的實(shí)際應(yīng)用帶來(lái)新曙光�；仡櫫随V（含鎂）系儲(chǔ)氫材料的研發(fā)歷程，闡述了各階段取得的標(biāo)志性進(jìn)展，分析和探討了今后的研究方向。

Abstract:

Magnesium-based (or magnesium-containing) materials are the promising solid hydrogen storage mediums due to the high gravimetric and volumetric hydrogen storage density. However, the high operation temperature, slow kinetics, and capacity decay severely limit their practical application. Based on the differences in chemical bonding, magnesium-based (or magnesium�瞔ontaining) storage materials are divided into alloys and coordination compounds. Over the past decades, much research has been undertaken to address the above mentioned issues through adjusting composition/structure, doping catalyst, micro-nanosizing and combing with other hydrides, resulting in significant improvements in kinetics rather than thermodynamics. Therefore, extra electric heating is still required to facilitate hydrogenation/dehydrogenation, which causes the low energy efficiency.Recent research focused on non-electrical heating energy, such as solar energy and waste heat, either directly or indirectly, providing new possibilities for the practical application of magnesium-based (or magnesium�瞔ontaining) hydrogen storage materials. This paper reviews the development of magnesium-based (or magnesium-containing) hydrogen storage materials and the milestones at each stage. Furthermore, the research direction is analyzed and discussed.